Concise, aromatization-based approach to an elaborate C2-symmetric pyrenophane.
نویسندگان
چکیده
A very short synthesis (5 steps), the crystal structure and resolution of an elaborate, inherently chiral [n](1,6)pyrenophane is reported. The synthesis hinges upon two very productive events: a multicomponent reaction and an unprecedented double-McMurry/valence isomerization/dehydrogenation step. Aromatization reactions are involved in the formation of all four of the rings of the pyrene system.
منابع مشابه
The (R,S)-symmetric and (R,S)-skew symmetric solutions of the pair of matrix equations A1XB1 = C1 and A2XB2 = C2
Let $Rin textbf{C}^{mtimes m}$ and $Sin textbf{C}^{ntimes n}$ be nontrivial involution matrices; i.e., $R=R^{-1}neq pm~I$ and $S=S^{-1}neq pm~I$. An $mtimes n$ complex matrix $A$ is said to be an $(R, S)$-symmetric ($(R, S)$-skew symmetric) matrix if $RAS =A$ ($ RAS =-A$). The $(R, S)$-symmetric and $(R, S)$-skew symmetric matrices have a number of special properties and widely used in eng...
متن کاملFuzzy Centroid-Based Method Applied to Customer Requirements Ranking in Diba Fiberglass Company
The purpose of this study is to introduce an application of fuzzy centroid-based approach to ranking the customer requirements using QFD with competition considerations for Diba Fiberglass, an Iranian Company. The illustrated approach, not only focuses on the normal fuzzy numbers, but also considers the non-normal fuzzy numbers to capture the true customer requirements. To this end, first, we p...
متن کاملThe concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes.
New C2-symmetric tetrafluorobenzobarrelene ligands were prepared and applied successfully to the rhodium-catalyzed asymmetric addition of arylboronic acids to aromatic aldehydes giving chiral diarylmethanols in high yield with high enantioselectivity.
متن کاملSynthesis of New C2-Symmetric Six-Membered NHCs and Their Application for the Asymmetric Diethylzinc Addition of Arylaldehydes
A concise method for the preparation of new 3,4,5,6-tetrahydropyrimidinium salts was presented in this paper. Further application of these salts in asymmetric diethylzinc addition of arylaldehydes was explored, giving the corresponding chiral second alcohols in good yields and moderate enantioselectivities.
متن کاملReduction of strained polycycles: how much strain can a pyrene anion take?
The reduction of a series of [n](2,7)pyrenophanes (n = 7-10) with lithium or potassium metal shows that the strain in the system, controlled by the length of the tether, determines the nature of the reduction products. The reduction of [7](2,7)pyrenophane (2) and [2]metacyclo[2](2,7)pyrenophane (3) leads to reductive dimerization followed by novel intramolecular sigma-bond formation as a means ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 48 62 شماره
صفحات -
تاریخ انتشار 2012